Regardless of whether or not you desire to have the CEO position permanently, you have it now and, I gather, for how long you don't know. To be effective for whatever period of time I believe you need to 'BE' the CEO rather than the CFO. As has been pointed out both others who have responded, the requirements of being effective in these two positions are quite different. Making the transition is a true call for "Break It Thinking".
My sincere suggestion is that you consider engaging a leadership coach who will assist you in making the transition and all that that means in relatively short order. Reading, of course, will be of value. The real challenge I find, is in implementing the changes that are really required and valuable to helping YOU be successful. I believe you will be well advised to see yourself as a long-term substitute rather than one called into the 'classroom' for a brief few-day stint. Who knows ... you may find you like it, you're good at it and you'd like to be the permanent CEO. Good luck to you.
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